A leak was discovered on a stainless steel pressure vessel, that showed large cracks that started underneath adhesive tape. Chloride stress corrosion cracking of austenitic stainless. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. What is stresscorrosion cracking and why does it occur. External chloride stress corrosion cracking of stainless. Prevention of chloride stress corrosion cracking cscc in austenitic stainless steel material for closed loop waterglycol mixture are as follows elimination of oxygen is an effective measure to prevent cscc in neutral and alkaline solutions. Stress corrosion cracking scc is a common issue with many specialty alloys. Higher temperatures reduce the permissible chloride level. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. This study explores the corrosion interactions between a metallic canister material, stainless steel ss 316, and an ibearing ceramic waste form, lead vanadoiodoapatite iapt, pb9.
Cscc can attack highly resistant austenitic stainless steel. Apr 14, 2015 this safety alert highlights the issue of chloride stress corrosion cracking of stainless steel lokring pipe connectors and advises dutyholders on actions required. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. The corrosion resistance of a stainless steel is dependent on the presence of an ultrathin protective oxide film passive film on its surface, but it is possible under certain conditions for this oxide film to break down, for example in halide solutions or reducing acids. I am specifying pipes for a water system with 500 ppm chloride in solution.
The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Current uses include food processing, brewery and winemaking equipment, hotwater tanks, heat exchanger tubing and automotive components. Pdf chloride induced stress corrosion cracking of type.
For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Stress corrosion cracking facts and how to reduce the. Chloride corrosion of carbon steel pipe engineering. So instead of the typical schedule 40 pipe, could i. The stainless steel was tested in the asreceived, the annealed and the quenched and tempered conditions with yield stresses of 233. The stress corrosion cracking scc susceptibility of 410 stainless steel in boiling 3% nacl solutions of ph 6. It requires a susceptible material and, depending on the material, sufficient levels of. It typically occurs in alloys, such as stainless steel, and not in pure metals. Higher naoh concentrations and exposure temperatures resulted in a reduced stability of the electrochemical passivity domain.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. The most pitting resistance is seen to be for the nitronic 50 stainless steel. Chloride stress corrosion cracking of a super duplex stainless steel. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Chloridechlorine levels and stainless steel alloy selection. Chloride cracking of 300 series stainless steels continues to occur in a. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Astm g123002015, standard test method for evaluating stress corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution, astm international, west conshohocken, pa, 2015. What forms of corrosion can occur in stainless steels. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. The effects of chloride content, oxygen content and solution ph were studied on test coupons with and without welds and on ubend specimens. Stress corrosion cracking facts and how to reduce the risk. Msr stress corrosion cracking scc is the unexpected, sudden failure of normally sound materials when subjected to tensile stress in a corrosive environment. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Chloride stress corrosion cracking cscc in stainless steel. The downhole pressure memory gauge cover which is the focal point of this. They are subject to crevice corrosion and pitting in chloride containing environments and are also.
Temperature and corrosion rate more complex than you. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. Chloride stress corrosion cracking ssina specialty steel. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and.
Stress corrosion cracking of an austenitic stainless steel. Stress corrosion cracking of 410 stainless steel in. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. Chloride stress corrosion cracking and 316 stainless steel. Ordinarily we would specify 316l stainless steel to limit the corrosion, but i was asked if we could instead specify carbon steel pipe with a corrosion allowance.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Chloride stress corrosion cracking is a well known form of scc, typically caused by. A strain rate of 5 x 10sup 4 minutesup 1 was employed. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316.
The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The resistance to localized corrosion of stainless steels in 20,000,100,000 and 200,000 ppm clsodium chloride solutions was investigated at 90c. The passive layer on stainless steel can be attacked by certain chemical species. Behaviour of stress corrosion cracking of austenitic stainless. Higher levels of chloride might cause crevice corrosion and pitting. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. High performance stainless steels nickel institute. The collapsed silver bridge, as seen from the ohio side. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature.
Overstressed ubends of types 304 and 347 stainless steels were exposed to water containing chloride ions to determine the susceptibility of these steels to stress corrosion cracking between the temperatures of 165 f and 200 f. What is the maximum chloride in ppm that can be allowed in. The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus. Harsh pitting corrosion is a localized damage that eats pits into stainless steel. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Addition of oxygen in autoclaves promoted the tendency to stress corrosion cracking. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. There is a synergistic relationship between dissolved oxygen and the chloride level. Chloride stress corrosion cracking in austenitic stainless. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. The cracks grew undetected behind thermal insulation.
Corrosion interactions between stainless steel and lead. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. Corrosion of unprotected carbon steel occurs even inside reinforced. Chloride stress corrosion cracking inspectioneering.
Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Chloride stress corrosion cracking in austenitic stainless steel. Although no stainless steel grade is totally immune. Elsayed building research institute, dokki, cairo egypt received november 8, 1982 summary the stress corrosion cracking scc susceptibility of 410 stainless steel in boiling 3% nacl solutions of ph 6. Corrosion behaviour of type 316l stainless steel in hot. Astm g123 002015 standard test method for evaluating. Chloride stress corrosion cracking of a super duplex. Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. This study is to identify factors responsible for loss of production due to problems in plant and equipment.
Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Chlorideinduced stress corrosion cracking of powder. Both of type 304 and type 316 stainless steels showed quite similar. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. The metals used most commonly as alloying elements in stainless steel include chromium, nickel, and molybdenum. This safety alert highlights the issue of chloride stress corrosion cracking of stainless steel lokring pipe connectors and advises dutyholders on actions required. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. The chlorideinduced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless steels dss was investigated and compared to the scc resistance of two commercial wrought forged dss. Reference is often made to stainless steel in the singular sense as if it were one material. This safety alert highlights the issue of chloride stress corrosion cracking which has been found to affect stainless steel grade 316316l lokring pipe connectors. Areas where the oxide film can break down can also sometimes be the result of the way components are designed. Stress corrosion cracking the international institute of. Stress corrosion cracking of an austenitic stainless steel in.
Chloride corrosion of carbon steel pipe engineering stack. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Chloride stress corrosion cracking of 300 series stainless. In addition to chloride ion, can be caused by elevated temperatures for extended. The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design.
Intergranular stress corrosion cracking of welded steel twi. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The corrosion behaviour of type 316l stainless steel in aqueous 3050 wt%. Chloride ion is the most common of these and is found in everyday materials such as salt and bleach. Stress corrosion cracking of 410 stainless steel in aqueous. Chloride stress corrosion involves selective attack of a metal along its grain boundaries.
So instead of the typical schedule 40 pipe, could i realistically use schedule 80 or 120 etc. Stainless steel grades 600 series this series of stainless steels grade is commonly referred to as precipitation hardening stainless steels. This limits the usefulness of austenitic stainless steel for containing. With chloride containing environments and stainless steel, there is usually a threshold. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. The corrosion also tends to occur in an environment where stress is applied to the components.
A common form of crevice failure occurs due to stress corrosion cracking. Pdf stress corrosion cracking of austenitic stainless. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly. On the stress corrosion cracking and hydrogen embrittlement. The combination of tensile stress and a specific corrosive environment can crack stainless steels. But once the passive film is overwhelmed by the increase in temperature, corrosion rate increases rapidly. Alloying metallic elements added during the making of the steel increase corrosion resistance, hardness, or strength. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i.
Stress corrosion cracking international institute of. Design guidelines for the selection and use of stainless steel nidl distributed by. The standard 304304l and 316316l grades are most susceptible. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. The effect of salt loading on chlorideinduced stress. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Chloride stress corrosion cracking of 300 series stainless steel. Hira ahluwalia, president, material selection resources inc.
Gouda national research centre, dokki, cairo egypt h. Three general classifications are used to identify stainless steels. This mode of attack is termed stress corrosion cracking scc. Exposure to room temperature environment showed parabolic weight loss behaviour, with corrosion rates of up to 0. As temperature increases, and as long as the passive film remains intact, corrosion rate does not increase.
Complete removal of oxygen by means of non scaling oxygen scavengers e. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. The stresscorrosion cracking of screws is a phenomenon where corrosionresistant materials, such as stainless steel, become cracked and damaged. Surface technology, 18 1983 327 339 327 stress corrosion cracking of 410 stainless steel in aqueous chloride solutions v. Corrosion of stainless steel in sodium chloride brine. Methods of minimizing chloride stress corrosion cracking. These steels can be heat treated to high strength levels.
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